(2,2′-Bipyridine-κ2 N,N′)chlorido(1,4,7-trithiacyclononane-κ3 S,S′,S′′)ruthenium(II) nitrate monohydrate
نویسندگان
چکیده
In the title compound, [RuCl(C(10)H(8)N(2))(C(6)H(12)S(3))]NO(3)·H(2)O or [RuCl(bpy)([9]aneS(3))]NO(3)·H(2)O, ([9]aneS(3) is 1,4,7-tri-thia-cyclo-nonane and bpy is 2,2'-bipyridine), the Ru(II) cation has a slightly distorted octa-hedral environment composed of three facially coordinated S atoms from ([9]aneS(3)), two N atoms from bpy and a chloride anion. The nitrate counter-ion and the water mol-ecule of crystallization are engaged in O-H⋯O hydrogen-bonding inter-actions, leading to a supra-molecular chain running parallel to the c axis.
منابع مشابه
(2,2′-Bipyridine-κ2 N,N′)bromido(1,4,7-trithiacyclononane-κ3 S,S′,S′′)ruthenium(II) hexafluoridophosphate
The title compound, [RuBr(C(10)H(8)N(2))(C(6)H(12)S(3))]PF(6) or [RuBr(bpy)([9]aneS(3))]PF(6) ([9]aneS(3) is 1,4,7-trithia-cyclo-nonane and bpy is 2,2'-bipyridine), exhibits a very similar octahedral coordination geometry for the Ru(2+) atom to that of its [RuCl(bpy)([9]aneS(3))](+) analogue, with only the chloride ligand being substituted by a bromide ligand. The presence of a PF(6) (-) anion ...
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